Hello-
These forums are largely focused on pure EV conversions, but we do have a few other people considering hybrid conversion concepts.
The easiest thing to do if you want a homebuilt hybrid seems to be to find an all-wheel drive car and disconnect the rear axle from the rest of the drivetrain and hook an electric motor straight to it, then add the rest of the EV components (batteries, controller, etc) to power it. In the case of a mini this would mean installing such an axle from another vehicle. The big disadvantage of this system would be even more weight than an EV conversion, since you did not save any weight by removing the engine, fuel tank, etc.
Another alternative would be to try and fit the drivetrain from a wrecked hybrid vehicle into the mini, but I know there is not much room in there; not sure what sort of micro-compact hybrids might be available in europe.
As for your idea, I'm not sure you could get enough power through the fan belt of the car to significantly assist the engine. And you'd still need an alternator or something else to run the 12V system in the car anyway.
Depending on your needs though, the mini would make a neat little (pure) EV.
What about a smart car diesel engine and transaxle? I bet that would work, though it isn't EV at all.
Good Luck.