Welcome to the forum.
Odd first question, unless you are prone to driving into water, I would suspect drowning would be more of an issue then electrocution from 48 volts.
Now, with some of the 200-300v conversions it may be something to consider...
One could approach an ICE car forum and ask if risk of explosion from the fuel is an issue. Most, I'm sure, wouldn't give it a second thought.