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lastly, I don't really understand the last part of your question "Is there a way to boost my pack voltage that little step while retaining regen?" so I couldn't really answer this part. maybe if you can elaborate a bit on this then myself or others in this forum can comment.
I assume that the concern is that the booster might not work in reverse, and so wouldn't allow the motor and inverter to charge the battery during regeneration.

By coincidence, many Toyota hybrids include a voltage doubler between the battery and inverter power stage (integrated into the controller/inverter) so the battery voltage is half of the maximum motor voltage, and they handle regenerative braking.
 
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