You do appear to be confused. The first-generation Chevrolet Volt battery pack contains 288 cells; the full pack voltage is not 288 volts.
This GM document describes the two generations of Volt battery pack:
VOLT_BATTERY.pdf
Yes, the nominal energy storage capacity of the first-generation Volt battery is 16 kWh, but those nine chunks are usually called "modules", not "batteries".
You certainly are confused! "kWh" is thousands of watt-hours, and watt-hours are not volts. Do you really not understand the difference between energy and voltage? Some basic electrical education may be in order... or maybe that was just a typo?
First, the full Volt battery pack voltage is 360 V, not 288 V. So half a Volt pack would be 180 V (nominal), not 144 V. I don't know if your controller can handle that.
The discussion of the combinations, though, is reasonable. Yes, you can string together fewer than the full set of modules to get a lower voltage and lower energy capacity, with the same peak current capability.
The 2kWh + 2kWh + 1kWh "block" is a set of modules which are bolted together in the Volt pack, so they are relatively easy to handle as one chunk, and there is work required to split that block into the three modules. If that combination works for you, a single block would be your car's entire battery pack... but it would have only 5 kWh of capacity, which isn't much.
A small correction: normally module voltages are the nominal voltage (sort of an average between fully charged and fully discharged), and for the first-generation Volt modules that's 45 V (~2 kWh) and 22.5 V (~1 kWh).