4x 12v batteries in series gives 48v that means neg from batt1 to pos batt2, neg batt2 to pos batt3, neg batt3 to pos batt4,
if 1 battery is given as 12v 10a the you have 48v 10a, for more amps you have to use larger batteries if you want to stay with 48v
IMO
larger batteries would give more capacity
...but, not "actually" more amps
I have used many 12V SLA batteries usually from 12V 12AH up to 12V 35AH
The 12V 12AH SLA's say (on the side of the battery) "Initial Current (less than 3.6A)
...but, I have pulled nearly 100A out of them many times
There is a tremendous voltage sag (watch the meter in the video)
...but, they do it
Here is a video where I did some "against the wall" tests
The tests were to see what kind of amps a ZY1020 48V 1,000W motor would draw
...but, it also shows what these small SLA batteries are capable of
https://www.youtube.com/watch?v=aVip7AKtHZg