David, I am curious if you could point me in the right direction for the data regarding the resting voltage for LiFePo4 cells. This is a very interesting discussion and I want the specs and/or data to look at with regard to what voltage a fully charged cell sits at. Are SE cells different than TS or any of the newer ones in regards to resting voltage?
Thanks,
Dave
Sorry for the delay in responding. I've been dealing with two family emergencies at once so I'm a bit behind.
This is really a bit OT for this thread but I'll post a few things to investigate. Unfortunately I haven't found a single definitive source for this information so I have had to glean from multiple sources including user's experience (and mine), user reports, technical papers and the like.
Watch this video for a good overall understanding to LiFePO4 cells. I recommend watching it more than once if you want to get a better understanding of things:
http://chargecar.org/blog/main/Battery_Tech_Talk
This paper is very technical. I originally read it to learn why manufacturers say not to charge LiFePO4 cells when they are below 0°C. If you know your physics and/or chemistry you can get some info out on voltages. It is not for the "faint of heart".
http://www.tinhoahoc.com/Battery/cr030203g.pdf
There used to be a CALIB spec sheet which showed 3.4V as the "float" voltage but I can no longer find it. I also had an email from someone who posted on the EVDL, they worked for a LiFePO4 battery manufacturer, that in testing that they could fully charge a cell if it were held at 3.4V long enough. I gathered that this was quite a long time but he didn't say how long. He also wouldn't disclose which manufacturer he worked for.
Jukka Järvinen has been testing and using LiFePO4 cells for many years. Search for his name on the EVDL and you will come up with posts by him. Basically he says that if a cell rests above 3.4V then it is evidence that all the Lithium has been moved from one side to the other indicating a fully charged cell. I do know that it takes very few ions to be transferred for the voltage to go from 0V to 3V so it makes sense that a similar thing happens at the fully charged end which my testing agrees with. For the older TS cells he said that they only need to be pushed to near 4V once in a while and at low currents. Charging them to lower voltages between them is definitely beneficial for life span.
Jack Rickard (evtv.me) has done quite a bit of battery testing but it takes a while before you can glean enough info from him to understand why he makes the claims he does. Over the past 2-3 years I have pieced together enough info from him to agree with him on the 3.4V number.
The documentation which came with my TS cells in 2009 say to stop charging when the current drops to 1% of what it was to start with where 0.5C was recommended. This would be an ending current of 0.005C which is quite low. Using this method left cells sitting above 3.5V for several days. I don't know how much of that was due to capacitance of the cells and how much was due to actual Li charge storage. Remember, these LiFePO4 cells are also big capacitors with their hundreds of plates separated by a dielectric.
Finally, the best thing you can do is get some cells and equipment and play with them.
HTH, now I'm going to keep watching this thread because I want to be able to program my Zivan chargers for LiFePO4 charging with both a voltage and current cutoff.