As you have already determined, it's hard to imagine that the thicker wires could be anything other than
Since there are no other pins in a NEMA 5 connector, there only remaining connection which makes sense for the thinner wires is to the line and neutral. Ford might have done this to allow the charger to read voltage at the plug, without voltage drop due to current flow in the thicker wires (which actually supply the charging current). Unfortunately, that's only a reasonable guess, and even if it is right which of the two thinner wires is which is unknown.
If you can open the charger case (without damaging it or causing other issues, such as with warranty coverage), perhaps you can see where the other end of the blue and tan wires go - that might provide a hint, although it's unlikely unless someone has posted internal details of the charger online.
black -> line pin
white -> neutral pin
green -> ground pin
white -> neutral pin
green -> ground pin
Since there are no other pins in a NEMA 5 connector, there only remaining connection which makes sense for the thinner wires is to the line and neutral. Ford might have done this to allow the charger to read voltage at the plug, without voltage drop due to current flow in the thicker wires (which actually supply the charging current). Unfortunately, that's only a reasonable guess, and even if it is right which of the two thinner wires is which is unknown.
If you can open the charger case (without damaging it or causing other issues, such as with warranty coverage), perhaps you can see where the other end of the blue and tan wires go - that might provide a hint, although it's unlikely unless someone has posted internal details of the charger online.