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I just realized I was mixed up. I was thinking about LiFePO4 voltages (2.5v-3.7v), not Lithium-ion pouch cells.
LiFePO4 cells are lithium-ion cells, and voltages don't depend on whether the cells are flat or cylindrical, or whether the flat cells are in pouches or prismatic boxes. So you were thinking about voltages of LiFePO4 cells (2.5v-3.7v), not the voltages of most other lithium-ion cells (with different electrode materials). Almost everyone makes this mistake.
 
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